Complexes of cadmium halides with 18-crown-6-ether
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چکیده
منابع مشابه
Ultraviolet photodepletion spectroscopy of dibenzo-18-crown-6-ether complexes with alkali metal cations.
Ultraviolet photodepletion spectra of dibenzo-18-crown-6-ether complexes with alkali metal cations (M(+)-DB18C6, M = Cs, Rb, K, Na, and Li) were obtained in the gas phase using electrospray ionization quadrupole ion-trap reflectron time-of-flight mass spectrometry. The spectra exhibited a few distinct absorption bands in the wavenumber region of 35 450-37 800 cm(-1). The lowest-energy band was ...
متن کاملLaser spectroscopic study on the conformations and the hydrated structures of benzo-18-crown-6-ether and dibenzo-18-crown-6-ether in supersonic jets.
The laser-induced fluorescence spectra of jet-cooled benzo-18-crown-6 (B18C6) and dibenzo-18-crown-6 (DB18C6) exhibit a number of vibronic bands in the 35 000-37 000 cm(-1) region. We attribute these bands to monomers and hydrated clusters by fluorescence-detected IR-UV and UV-UV double resonance spectroscopy. We found four and two conformers for bare B18C6 and DB18C6, and the hydration of one ...
متن کاملDibenzo-18-crown-6
The asymmetric unit of the title compound, C(20)H(24)O(6), contains two mol-ecules that are identical within standard deviations concerning bond lengths and angles as well as their conformations. In the crystal structure, weak C-H⋯O inter-actions help to consolidate the packing.
متن کامل(18-Crown-6)(trifluoromethanesulfonato)sodium
The title compound, [Na(CF(3)O(3)S)(C(12)H(24)O(6))], features a sodium cation that is coordinated by eight O atoms in an irregular hexa-gonal bipyramidal environment. The equatorial positions are occupied by the six O atoms of an 18-crown-6 ether ring. In the axial positions, there is one O atom of a trifluoro-methane-sulfonate anion and an ether O atom of a symmetry-equivalent crown ether rin...
متن کامل18-Crown-6 and dibenzo-18-crown-6 assisted extraction of cesium from water into room temperature ionic liquids and its correlation with stability constants for cesium complexes.
The pH-profiles of the extraction of Cs(+) into four conventional (1-butyl-3-methylimidazolium hexafluorophosphate and bis[trifluoromethyl)sulphonyl]imides of 1-butyl-3-methylimidazolium, 1-hexyl-3-methylimidazolium, and 1-(2-ethylhexyl)-3- methylimidazolium) and two novel (trioctylmethylammonium salicylate and tetrahexylammonium dihexylsulfosuccinate) room temperature ionic liquids have been d...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section A Foundations of Crystallography
سال: 1987
ISSN: 0108-7673
DOI: 10.1107/s0108767387080619